Optical and electronic properties of air-stable organoboron compounds with strongly electron-accepting bis(fluoromesityl)boryl groups† †Electronic supplementary information (ESI) available: Experimental details. Additional views of the molecular structures from X-ray diffraction. Cyclic voltammograms of 2 and 3. Plots of calculated lowest energy transitions versus UV-visible absorption spectra. Variable-temperature emission and excitation spectra. Copies of all NMR spectra. Cartesian coordinates of all optimised geometries. CCDC 1010408–1010412. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c4sc02410a Click here for additional data file. Click here for additional data file.

5,20-Bis(α-oligothienyl)-substituted [26]hexaphyrins possessing electronic circuits strongly perturbed by meso-oligothienyl substituents† †Electronic supplementary information (ESI) available: General experimental methods, HR-ESI-TOF mass spectra, UV/Vis absorption spectra, NMR spectra, cyclic voltammograms, X-ray crystal structures and results of DFT calculations. CCDC 1025770, 1025771 and 1025772. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c4sc03394a Click here for additional data file. Click here for additional data file.

Department of Chemistry, Graduate Schoo Kyoto 606-8502, Japan. E-mail: osuka@kuc Spectroscopy Laboratory for Functional p Chemistry Yonsei University, Seoul 120-749 † Electronic supplementary information methods, HR-ESI-TOF mass spectra, UV cyclic voltammograms, X-ray crystal struc CCDC 1025770, 1025771 and 1025772. Fo or other electronic format see DOI: 10.103 Cite this: Chem. Sci., 2015, 6, 1696

Crystalline boron-linked tetraaminoethylene radical cations† †Electronic supplementary information (ESI) available: NMR spectra, crystallographic data, crystal structures, UV-vis spectra, cyclic voltammograms, EPR spectra, and theoretical calculation. CCDC 1548460–1548466. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7sc03528d Click here for additional data file. Click here for additional data file.

Dynamic induction of enantiomeric excess from a prochiral azobenzene dimer under circularly polarized light† †Electronic supplementary information (ESI) available: Synthesis, 1H NMR spectra, 13C NMR spectra, UV absorption plots, HPLC traces, and CD spectra of the compounds; crystallographic information files. CCDC 1003754. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c4sc01993h Click here for additional data file. Click here for additional data file.

Inner-sphere vs. outer-sphere reduction of uranyl supported by a redox-active, donor-expanded dipyrrin† †Electronic supplementary information (ESI) available: General procedures, synthetic details, NMR spectra, EPR spectra, IR spectra, electronic absorption and emission spectra, voltammetric data, X-ray crystallographic data, computational details and optimised geometries. CCDC 1446511, 1446512 and 1507634. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c6sc02912d Click here for additional data file. Click here for additional data file.

EaStCHEM School of Chemistry, The Unive David Brewster Road, Edinburgh, EH9 3FJ, [email protected] LPCNO, INSA, Université de Toulouse, 13 cedex 4, France Centre for Radiochemisty Research, Sch Manchester, Oxford Road, Manchester, M13 WestCHEM School of Chemistry, University † Electronic supplementary information synthetic details, NMR spectra, EPR spe and emission spectra, voltammetric computati...

Dicyano- and tetracyanopentacene: foundation of an intriguing new class of easy-to-synthesize organic semiconductors† †Electronic supplementary information (ESI) available: Experimental details (synthesis and solubility, NMR spectra, cyclic voltammetry, UV-Vis absorption/stability tests, thermal analysis, X-ray diffraction, theoretical calculations, optical microscopy and scanning electron microscopy, transistor fabrication and electrical characterization). CCDC 1443834 and 1519904. For crystallographic data in CIF or other electronic format see DOI: 10.1039/c7tc00143f Click here for additional data file. Click here for additional data file.